Abstract
Copper ion is a type of micronutrients and plays important roles in metabolic processes of organisms. Copper ion can act as an essential cofactor of various enzymes such as nitrate reductase, cytochrome oxidase, and superoxide dismutase.
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Bai Y, Ruan X, Mo J, Xie Y (1998) Potentiometric stripping analysis of copper using cysteine modified mercury film electrode. Anal Chim Acta 373:39–46
Brady DC, Crowe MS, Turski ML, Hobbs GA, Yao X, Chaikuad A, Knapp S, Xiao K, Campbell SL, Thiele DJ (2014) Copper is required for oncogenic BRAF signalling and tumorigenesis. Nature 509:492
Burchfield H (1958) Molecular rearrangement in the reaction of cysteine with 1-fluoro-2, 4-dinitrobenzene. Nature 181:49
Chan M-S, Huang S-D (2000) Direct determination of cadmium and copper in seawater using a transversely heated graphite furnace atomic absorption spectrometer with Zeeman-effect background corrector. Talanta 51:373–380
Chan Y-H, Chen J, Liu Q, Wark SE, Son DH, Batteas JD (2010) Ultrasensitive copper (II) detection using plasmon-enhanced and photo-brightened luminescence of CdSe quantum dots. Anal Chem 82:3671–3678
Chow CK (1979) Nutritional influence on cellular antioxidant defense systems. Am J Clin Nutr (USA)
Dai B, Cao M, Fang G, Liu B, Dong X, Pan M, Wang S (2012) Schiff base-chitosan grafted multiwalled carbon nanotubes as a novel solid-phase extraction adsorbent for determination of heavy metal by ICP-MS. J Hazard Mater 219:103–110
de Graaf-Hess A, Trijbels F, Blom H (1999) New method for determining cystine in leukocytes and fibroblasts. Clin Chem 45:2224–2228
Ehrenberg L, Harms-Ringdahl M, Fedorcsak I, Granath F (1989) Kinetics of the copper-and iron-catalysed oxidation of cysteine by dioxygen. Acta Chem Scand 43:177–187
Elliott KAC (1930) On the catalysis of the oxidation of cysteine and thioglycollic acid by iron and copper. Biochem J 24:310
Fang Y-M, Song J, Chen J-S, Li S-B, Zhang L, Chen G-N, Sun J-J (2011) Gold nanoparticles for highly sensitive and selective copper ions sensing—old materials with new tricks. J Mater Chem 21:7898–7900
Fischer LM, Pedersen C, Elkjær K, Noeth N-N, Dohn S, Boisen A, Tenje M (2011) Development of a microfabricated electrochemical-cantilever hybrid platform. Sens Actuators B Chem 157:321–327
Flemming C, Trevors J (1989) Copper toxicity and chemistry in the environment: a review. Water Air Soil Pollut 44:143–158
Hsiao Y-P, Su W-Y, Cheng J-R, Cheng S-H (2011) Electrochemical determination of cysteine based on conducting polymers/gold nanoparticles hybrid nanocomposites. Electrochim Acta 56:6887–6895
Kim YR, Kim HJ, Kim JS, Kim H (2008) Rhodamine-based “turn-on” fluorescent chemodosimeter for Cu (II) on ultrathin platinum films as molecular switches. Adv Mater 20:4428–4432
Lee T-Y, Notari RE (1987) Kinetics and mechanism of captopril oxidation in aqueous solution under controlled oxygen partial pressure. Pharm Res 4:98–103
Lima GF, Ohara MO, Clausen DN, Nascimento DR, Ribeiro ES, Segatelli MG, Bezerra MA, Tarley CR (2012) Flow injection on-line minicolumn preconcentration and determination of trace copper ions using an alumina/titanium oxide grafted silica matrix and FAAS. Microchim Acta 178:61–70
Lin M, Hu X, Ma Z, Chen L (2012) Functionalized polypyrrole nanotube arrays as electrochemical biosensor for the determination of copper ions. Anal Chim Acta 746:63–69
Lindroth P, Mopper K (1979) High performance liquid chromatographic determination of subpicomole amounts of amino acids by precolumn fluorescence derivatization with o-phthaldialdehyde. Anal Chem 51:1667–1674
Liu A-C, Chen D-C, Lin C-C, Chou H-H, Chen C-H (1999) Application of cysteine monolayers for electrochemical determination of sub-ppb copper (II). Anal Chem 71:1549–1552
Liu R, Chen Z, Wang S, Qu C, Chen L, Wang Z (2013) Colorimetric sensing of copper (II) based on catalytic etching of gold nanoparticles. Talanta 112:37–42
Lou T, Chen L, Chen Z, Wang Y, Chen L, Li J (2011) Colorimetric detection of trace copper ions based on catalytic leaching of silver-coated gold nanoparticles. ACS Appl Mater Interfaces 3:4215–4220
Lu J, Sun C, Chen W, Ma H, Shi W, Li X (2011) Determination of non-protein cysteine in human serum by a designed BODIPY-based fluorescent probe. Talanta 83:1050–1056
Luo D, Smith SW, Anderson BD (2005) Kinetics and mechanism of the reaction of cysteine and hydrogen peroxide in aqueous solution. J Pharm Sci 94:304–316
Meites L, Meltes T (1948) Removal of oxygen from gas streams. Anal Chem 20:984–985
Pecci L, Montefoschi G, Musci G, Cavallini D (1997) Novel findings on the copper catalysed oxidation of cysteine. Amino Acids 13:355–367
Pirie NW (1931) The oxidation of sulphydryl compounds by hydrogen peroxide: catalysis of oxidation of cysteine and glutathione by iron and copper. Biochem J 25:1565
Rigo A, Corazza A, di Paolo ML, Rossetto M, Ugolini R, Scarpa M (2004) Interaction of copper with cysteine: stability of cuprous complexes and catalytic role of cupric ions in anaerobic thiol oxidation. J Inorg Biochem 98:1495–1501
Salaün P, van den Berg CM (2006) Voltammetric detection of mercury and copper in seawater using a gold microwire electrode. Anal Chem 78:5052–5060
Sanger F (1945) The free amino groups of insulin. Biochem J 39:507
Shen Q, Li W, Tang S, Hu Y, Nie Z, Huang Y, Yao S (2013) A simple “clickable” biosensor for colorimetric detection of copper (II) ions based on unmodified gold nanoparticles. Biosens Bioelectron 41:663–668
Shindo H, Brown TL (1965) Infrared spectra of complexes of l-cysteine and related compounds with zinc (II), cadmium (II), mercury (II), and lead (II). J Am Chem Soc 87:1904–1909
Stasser JP, Siluvai GS, Barry AN, Blackburn NJ (2007) A multinuclear copper (I) cluster forms the dimerization interface in copper-loaded human copper chaperone for superoxide dismutase. Biochemistry 46:11845–11856
Tang S-S, Chang G-G (1995) Nucleophilic aromatic substitution of glutathione and 1-chloro-2, 4-dinitrobenzene in reverse micelles. A model system to assess the transition-state stabilization in glutathione transferase catalyzed conjugation. J Org Chem 60:6183–6185
Trumbore CN, Ehrlich RS, Myers YN (2001) Changes in DNA conformation induced by gamma irradiation in the presence of copper. Radiat Res 155:453–465
Wang X, Chen L, Chen L (2014) Colorimetric determination of copper ions based on the catalytic leaching of silver from the shell of silver-coated gold nanorods. Microchim Acta 181:105–110
Witting PK, Bowry VW, Stocker R (1995) Inverse deuterium kinetic isotope effect for peroxidation in human low-density lipoprotein (LDL): a simple test for tocopherol-mediated peroxidation of LDL lipids. FEBS Lett 375:45–49
Wu J, Boyle EA (1997) Low blank preconcentration technique for the determination of lead, copper, and cadmium in small-volume seawater samples by isotope dilution ICPMS. Anal Chem 69:2464–2470
Xia X, Long Y, Wang J (2013) Glucose oxidase-functionalized fluorescent gold nanoclusters as probes for glucose. Anal Chim Acta 772:81–86
Yin K, Li B, Wang X, Zhang W, Chen L (2015) Ultrasensitive colorimetric detection of Cu2+ ion based on catalytic oxidation of l-cysteine. Biosens Bioelectron 64:81–87 (Reproduced with Permission. Copyright (2015) Elsevier)
Yu C, Chen L, Zhang J, Li J, Liu P, Wang W, Yan B (2011) “Off-On” based fluorescent chemosensor for Cu2+ in aqueous media and living cells. Talanta 85:1627–1633
Yuan Z, Cai N, Du Y, He Y, Yeung ES (2013) Sensitive and selective detection of copper ions with highly stable polyethyleneimine-protected silver nanoclusters. Anal Chem 86:419–426
Zhang L, Zhu J, Ai J, Zhou Z, Jia X, Wang E (2013) Label-free G-quadruplex-specific fluorescent probe for sensitive detection of copper (II) ion. Biosens Bioelectron 39:268–273
Zhang X, Zhao T, Cheng T, Liu X, Zhang H (2012) Rapid resolution liquid chromatography (RRLC) analysis of amino acids using pre-column derivatization. J Chromatogr B 906:91–95
Zhou Y, Wang S, Zhang K, Jiang X (2008) Visual detection of copper (II) by azide-and alkyne-functionalized gold nanoparticles using click chemistry. Angew Chem Int Ed 47:7454–7456
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Yin, K. (2020). An Ultrasensitive Colorimetric Biosensor for Copper Ion Detection. In: Design of Novel Biosensors for Optical Sensing and Their Applications in Environmental Analysis. Springer Theses. Springer, Singapore. https://doi.org/10.1007/978-981-13-6488-4_4
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